I want to say, most likely no. That will not work that well. It will give you a lot of useful trainer cards but other than that, meh. You need to decide what kind of deck you want to build and just buy singles most likely. Atm the cheaper decks that still do well that come to mind are.
-Tool Time (Trubbish/Sigilyph): A fun deck that relies on tools to attack. Its pretty good but its almost imperative that you go first to be successful. It has a lot of weaknesses that people dont seem to like to discuss, saying its a really good deck. I honestly have never lost to it on the PTCGO, using a bunch of rogue decks.
-Dragonite/Garbodor: One of my favorite decks atm. Once you get set up, it prevents items and abilities. Pretty much one of the most frustrating decks to play against, for certain decks. I have had a lot of success with this deck. But it can have issues setting up both, and has trouble against other dragon decks. Other than that, the top tier decks can also give this deck some trouble. Win % on PTCGO roughly 70%
-Beedrill: My current favorite deck. It is fairly cheap if you forgo the Virizion Ex. Which it can work without, but i prefer to have 1 in it. It plays off beedrills cheap 1 energy attack that does 60 damage, poisons and confuses, but it needs to be at full hp or it only does 20. With the stadium card, virbank city gym. It adds 2 damage counters between turns to poison pokemon. This deck has to run max potions and other ways to keep the beedrill healthy. But all in all it forces tons of switches that can mess up an opponents field. Either way you will be spending more on trainer cards than the pokemon, since the most expensive pokemon is like a $1.50 or something. My win % is currently 80% on PTCGO.
-Empoleon: This deck is runs on 1 energy as well. Empoleon does 10 damage x the number of pokemon on the field, being up to 120. The list i use also has 2 keldeo exs that can be bought like $7 ish as a single, or like $16 is as a tin with 4 packs. A pretty good deal. Either way this deck is pretty fun and reliable, though it has issues against deck that run very few pokemon on the field. Though with the metagame as it is now, it isn't much of a problem. My win % is about 60%
Anyway if you want sample lists or skeletons for these decks pm me or something.